Determination of the Ionization Potential of Xenon
Theory
Ionization potential (or ionization energy) is the minimum energy required to remove an electron from a gaseous atom or ion. For Xenon (Xe), this can be determined experimentally by studying the relationship between the applied voltage and the ionization current in a discharge tube containing xenon gas.
When an increasing voltage is applied to a xenon-filled discharge tube, electrons gain kinetic energy. At a critical voltage, electrons acquire enough energy to ionize xenon atoms by knocking out electrons. This results in a sharp increase in current, indicating ionization. The corresponding voltage at which this occurs is the ionization potential of xenon.
Apparatus
- Xenon gas discharge tube
- High-voltage DC power supply
- Microammeter (to measure current)
- Voltmeter (to measure voltage)
- Resistors (for controlling current flow)
- Connecting wires
- Rheostat (for adjusting voltage smoothly)
Procedure
- Setup the circuit: Connect the xenon discharge tube to the DC power supply with a microammeter in series and a voltmeter in parallel.
- Initial readings: Set the voltage to zero and gradually increase it in small steps.
- Observe current: Note the microammeter readings at different applied voltages.
- Detect ionization threshold: Identify the voltage at which a sudden increase in current occurs. This is the ionization potential of xenon.
- Record data: Tabulate voltage and current values, marking the ionization point.
- Repeat measurements: Take multiple readings to ensure accuracy.
Calculation Formula
The ionization potential (ϕ) of xenon is determined as: Where:
- = Ionization potential (eV)
- = Charge of an electron (1.602 \times 10^{-19} C)
- = Ionization voltage (V) determined from the experiment
Precautions
- Ensure proper electrical connections to avoid fluctuations in readings.
- Increase voltage gradually to prevent damage to the discharge tube.
- Avoid external light interference as it may affect readings.
- Use a stable power supply for consistent voltage output.
- Take multiple readings and use an average value for accurate results.
By following this method, the ionization potential of xenon can be accurately determined.