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 Determination of the Ionization Potential of Xenon

Theory

Ionization potential (or ionization energy) is the minimum energy required to remove an electron from a gaseous atom or ion. For Xenon (Xe), this can be determined experimentally by studying the relationship between the applied voltage and the ionization current in a discharge tube containing xenon gas.

When an increasing voltage is applied to a xenon-filled discharge tube, electrons gain kinetic energy. At a critical voltage, electrons acquire enough energy to ionize xenon atoms by knocking out electrons. This results in a sharp increase in current, indicating ionization. The corresponding voltage at which this occurs is the ionization potential of xenon.

Apparatus

  1. Xenon gas discharge tube
  2. High-voltage DC power supply
  3. Microammeter (to measure current)
  4. Voltmeter (to measure voltage)
  5. Resistors (for controlling current flow)
  6. Connecting wires
  7. Rheostat (for adjusting voltage smoothly)

Procedure

  1. Setup the circuit: Connect the xenon discharge tube to the DC power supply with a microammeter in series and a voltmeter in parallel.
  2. Initial readings: Set the voltage to zero and gradually increase it in small steps.
  3. Observe current: Note the microammeter readings at different applied voltages.
  4. Detect ionization threshold: Identify the voltage at which a sudden increase in current occurs. This is the ionization potential of xenon.
  5. Record data: Tabulate voltage and current values, marking the ionization point.
  6. Repeat measurements: Take multiple readings to ensure accuracy.

Calculation Formula

The ionization potential (ϕ) of xenon is determined as: ϕ=eV\phi = eV Where:

  • ϕ\phi = Ionization potential (eV)
  • ee = Charge of an electron (1.602 \times 10^{-19} C)
  • VV = Ionization voltage (V) determined from the experiment

Precautions

  1. Ensure proper electrical connections to avoid fluctuations in readings.
  2. Increase voltage gradually to prevent damage to the discharge tube.
  3. Avoid external light interference as it may affect readings.
  4. Use a stable power supply for consistent voltage output.
  5. Take multiple readings and use an average value for accurate results.

By following this method, the ionization potential of xenon can be accurately determined.

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